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What To Consider When Using Additives In Powder Coatings

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Powder coating additives are chemicals added to the powder coating base material that can help obtain different mechanical properties. So, what should we consider when applying additives in powder coatings?

Compatibility With The Resin

This is the first issue that should be noted when selecting additives. Powder coating additives must exist steadily in the powder coating in a long term in order to play its proper performance. So general additives must have compatibility with different resins, such as epoxy, polyester, acrylic and others.

Usually the method to compare the compatibility of these additives with resin is based on the similarity of their structures. For example, the leveling agent is a main additive in the production of powder coatings. It can reduce the difference in surface tension of the coating film, make the film more uniform and eliminate porosity, so that the cured coating film can obtain a smooth and glossy surface.

More specifically, additives with carriers, such as the E-12 carrier, can not be applied in the formulation with pure polyester system. Also, the commonly used B-68 type chemical matting agent containing cyclic ether and polyacid is only suitable for epoxy system. When used in other resins, it will bring negative impact on the coating film.

 

Resin In Powder Coatings-

Adaptability To The Production Process

When designing the formulation for powder coating additives, it should be considered that some harsh conditions like high temperature, low temperature, or high-speed shear, may cause the decomposition and volatilization of powder coating additives, resulting in formulation failure.

In the mixing of two or more additives and the base material, the additives must be fully dispersed in the powder coating base material for full effectiveness. They can be mixed with the base material in a different order of addition.

For example, there are 4 ways to add additives A and B to the powder coating.

(1) Base material + A → premix → extruding, crushing + B → sieving, finished product, packaging

(2) Base material + B → premix → extruding, crushing + A → sieving, finished product, packaging

(3) Base material + A + B → premix → extruding, crushing → sieving, finished product, packaging

(4) Base material → premix → extruding, crushing + A + B → sieving, finished product, packaging

If there are 3 or more kinds of additives, there will be more ways of dispersion considering the setting of processing parameters.

Experiment fully proves that the sequence and each step of processing conditions are very important for mixing various additives with base materials, which directly affects the mixing effect and the performance of the finished coating film.

Diversity Of The Functions

In addition to the main functions, some powder coating additives also have two or more functions. Thus, we must take this into account and adjust the amount in the formulation or simplify the formulation when designing the powder coating formulation.

For example, zinc oxide is a common chemical. It can replace part of the titanium dioxide as white pigment. It has certain electrical conductivity for anti-static or electrical conductivity occasions. And it also has the functions of shielding ultraviolet rays, anti-mildew and sterilization, and can improve the performance of coatings containing carboxyl group resins. As you can see, understanding its various functions is important to choose an effective additive.

 

Different Types of Powder Coatings-

Mutual Effects Between Powder Coating Additives

The mutual effect of powder coating additives refers to the synergistic effect of two or more additives when used in conjunction with each other. Of course, the opposite of synergistic effect is confrontation effect.

For example, carbon black and thiophenolic antioxidants in pure polyester outdoor powder coatings have excellent synergistic antioxidant effect. However, when used together with amine or phenolic antioxidants, the coating film stability is weakened by the antagonistic effect.

Limitati on Of The Powder Coatings

The application of powder coating additives is often limited to the end use of the coating film. Different kinds of powder coatings has different requirements on the features of the additives, including color, odor, pollution resistance, durability, electrical conductivity, heat and cold resistance, etc.

Summary

In addition to the above things, we should also consider the toxicity of the additive. If conditions permit, use as less TGIC products as possible because TGIC contains a certain amount of toxicity.

Powder coating additives are very important for powder coatings because they have properties that can enhance certain special properties of powder coatings or reduce the appearance of some film defects.

With the growth of China’s powder coating industry and the further development of powder coating additives, the importance of powder coating additives will become more obvious and the development space will be more extensive.

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Dennis

Hi, I'm the author of this post. We have 22 years of experience in the manufacturing and supplying of flexible packaging films. We have helped over 400 customers in over 30 countries with high-quality plastic film products such as BOPP, BOPET, BOPA, CPP film, etc., which are widely used in plastic flexible packaging and paper-plastic composites, graphic. If you have any requests, get in touch with us for free quote and one-stop solution for your market.

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